The coupling reaction of phenylcthynyltributyltin with (4-trifluoromethyl)iodobenzene catalyzed by a Pd(0) complex coordinated by N-(2-diphenylphosphinobenzylidene)-2-phenylethylamine was found to start with oxidative addition of the tin reagent to the Pd(0) complex. In contrast, the use of 1,3-bis(
On the regioselectivity of palladium catalyzed cross-coupling reactions of alkenylsilanes: Participation of β-cationic organosilicate-palladium species during the transmetallation
✍ Scribed by Yasuo Hatanaka; Ken-ichi Goda; Tamejiro Hiyama
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 431 KB
- Volume
- 465
- Category
- Article
- ISSN
- 0022-328X
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