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On the Reactivity of the Iminodiphosphane C6H4(o-CN)N=PPh2−PPh2: Fragmentation Versus Isomerisation

✍ Scribed by Zhaofu Fei; Rosario Scopelliti; Paul J. Dyson

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
193 KB
Volume
2004
Category
Article
ISSN
1434-1948

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On the Ambident Behaviour of Dicyanmetha
On the Ambident Behaviour of Dicyanmethanidonitrite; Syntheses and Characterization of Complexes of the Type [M{N(O)C(CN)2}(PPh3)n] (M = CuI, AgI; n = 2, 3)
✍ Lothar Jäger; Carola Tretner; Helmut Hartung; Matthias Biedermann 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 279 KB 👁 2 views

Complexes of the type [M{N(O)C(CN) 2 }(PPh 3 ) n ] (M = Cu I , oxygen atom (silver). In addition the two copper and silver complexes [M{N(O)C(CN) 2 }(PPh 3 ) 2 ] 2 are not isostructural but Ag I , n = 2, 3) were synthesized by metathesis of K[N(O)C(CN) 2 ] and [M(NO 3 )(PPh 3 ) n ]. The complexes we