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On the reactivity of isoxazoles with Mo(CO)6

✍ Scribed by Donato Donati; Serena Ferrini; Stefania Fusi; Fabio Ponticelli

Publisher
Journal of Heterocyclic Chemistry
Year
2004
Tongue
English
Weight
176 KB
Volume
41
Category
Article
ISSN
0022-152X

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✦ Synopsis

Abstract

Ring opening with molybdenum hexacarbonyl of functionalized isoxazoles is a valuable synthetic process. Tetrazolopyridine 4 and pyrazolopyridine 9 were obtained from isoxazolopyridines 3 and 6, respectively, whereas the isoxazole 14 gave ketone 16 through the intermediate 17.

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