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On the reaction of nickel(II) with thiocyanate ion and other unidentate ligands in dimethylsulfoxide as solvent:IdorDmechanism?

✍ Scribed by J. F. Coetzee; E. Hsu

Book ID: 104861102
Publisher: Springer US
Year: 1975
Tongue: English
Weight: 412 KB
Volume: 4
Category: Article
ISSN: 0095-9782
DOI: 10.1007/bf00646051

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## Abstract The kinetics of reversible complexation of oxalatopentaammine cobalt(III) with Ni^2+^ has been investigated in MeOH + water media (0–50 (v/v) % MeOH) at 15.0–35.0°C and I = 0.10 mol dm^−3^. Analysis of rate data indicates that the monobonded complex [(NH~3~)~5~ · CoOCOCO~2~Ni]^3+^ in wh