On the quadrupole splitting of a low-spin Iron(III)-Dithio Chelate

✍ Scribed by W.M. Reiff; D. Szymanski

• Publisher: Elsevier Science
• Year: 1972
• Tongue: English
• Weight: 237 KB
• Volume: 17
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(72)87076-3

✦ Synopsis

The magnetically wrturbed hiijssbauer spectra of iron(III) (dithioacetylscetonate)J show 'I,-< 0 corresponding to a dx,, hole and a *A sound term. These results support a recent study of the temperature dependence of the quadrupole splitting and suggest that the origin of the quadrupole splitting is ptiarily in the distribution of nortbonding electrons_ '. ,.