✦ LIBER ✦

On the possibility of dielectric saturation in molecular systems

✍ Scribed by Toshiaki Kakitani; Noboru Mataga

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 393 KB
Volume: 124
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)85049-7

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✦ Synopsis

Using the model of dielectric continuum and Lorentz's field, we have demonstrated that the polarization of the first coordinated shell of the solvent molecules around a charged solute molecule is weakly saturated. The dielectric saturation effect has also been observed in the calculated result that the ratio between the equilibrium and non-equilibrium free energies considerably deviates from unity which is expected m the absence of dielectric saturation.

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