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On the Photomagnetic Properties of the Binuclear Spin Crossover Complexes {[Fe(bt)(NCSe)2]2(bpym)} and {[Fe(bpym)(NCSe)2]2(bpym)}

✍ Scribed by Nawel Ould Moussa; Shinichiro Mouri; Gábor Molnár; Koichiro Tanaka; José Antonio Real; Azzedine Bousseksou


Book ID
106416913
Publisher
Springer
Year
2007
Tongue
English
Weight
358 KB
Volume
18
Category
Article
ISSN
1053-0495

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## Abstract The dinuclear iron(II) complex {[Fe(CH~3~bipy)(NCS)~2~]~2~bpym} has been synthesised and its crystal structure determined at 293 K. The magnetic properties display intramolecular antiferromagnetic coupling at 1 bar (__J__ = −4.2 cm^−1^), and the onset of a pressure‐induced spin conversi

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## Abstract The mono‐ and binuclear organometallic Ni^II^ complexes [(μ‐bpym){Ni(Mes)Br}__~n~__] (bpym = 2,2′‐bipyrimidine; __n__ = 1 or 2; Mes = mesityl = 2,4,6‐trimethylphenyl) were prepared and characterised electrochemically and spectroscopically (NMR, UV/Vis/NIR) in detail. The long‐wavelength