๐”– Bobbio Scriptorium
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On the Photochemical Stability of the 9-Mesityl-10-methylacridinium Cation

โœ Scribed by Andrew C. Benniston; Kristopher J. Elliott; Ross W. Harrington; William Clegg


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
625 KB
Volume
2009
Category
Article
ISSN
1434-193X

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The chemiluminescent reaction of an acridinium ester (AE) requires addition of peroxide to the 9 position of the acridinium ring. The addition of a hydroxide ion t o the 9 position of an acridinium ester t o form the carbinol adduct has also been well documented. We have observed a similar addition

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The ENDOR spectrum of fhe V.lO-d~propylant~cne (DPA) Q~IO". genmntcd by ou&tlon ,=.f DPA m CHIC& =,,\_ mnmg = 10% CF,COOH and 6% (CFsCO)IO. stihrblts clwl~ the evlstence of the duner and monomer cation species The heat of dlssoclatlon of the dlmer catlon m CH2C12 IS estimated to be 22 3 kJ mol-'