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On the origin of the rotational state dependence of the decay of intermediate case molecules. Role of angular momentum selection rules in intersystem crossing

✍ Scribed by Y. Matsumoto; L.H. Spangler; D.W. Pratt

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 695 KB
Volume: 98
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80218-8

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✦ Synopsis

Experimental and theoretical studies of the role of angular momentum in the decay behavior of ' Bsu pyrazine show that the strong rotational state dependence has its origin in the breakdown of the bp = 0 (AK = ~1) selection rule for intersystem crossing. Some possible reasons for this are discussed.