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On the origin of the anomalous ultraslow solvation dynamics in heterogeneous environments

✍ Scribed by Kankan Bhattacharyya; Biman Bagchi


Book ID
107584335
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
2007
Tongue
English
Weight
460 KB
Volume
119
Category
Article
ISSN
0253-4134

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Solvation dynamics versus inhomogeneity
✍ Achim Wagener; Ranko Richert πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 530 KB

The recent discussion on the origin of spectral shifts observed for the luminescence of sensor molecules in fluid solution has guided us to reinvestigate solvation dynamics data in glassy matrices. It is demonstrated that the Stokes shift of a phosphorescent probe in a supercooled liquid is of pure