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On the novel reactivity of t-butyldimethylsilyl ether in prostaglandin synthesis: application to total synthesis of 11-epi-PGF2α

✍ Scribed by Yasuhiro Torisawa; Masakatsu Shibasaki; Shiro Ikegami


Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
233 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis


Smmary:

A facile 1,5-migration of a t-butyldimethylsilyl group and a new cleavage reaction of t-butyldimethylsilyl ether to alcohol in prostaglandin intermediates are described.