On the non-local electrostatic theory of hydration force
β Scribed by A.A. Kornyshev
- Publisher
- Elsevier Science
- Year
- 1986
- Weight
- 412 KB
- Volume
- 204
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
We have considered variations in dielectric polarization over distances comparable to molecular dimensions in the Ice structure and ir. aqueous media. The decay of polarization away from a surface and the associated "hydration force" have been studied analytic&y in ice and by molecular dynnmics in w
A model, consisting of a pair of large macroions in a dipolar hard sphere-point ion electrolyte, is considered in order to evaluate the hydration force (solvent-mediated) contribution to the force between colloidal particles, which is missing in the DLVO theory. Using the mean spherical approximatio