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On the Necessity of Using Activities in the Gibbs Equation

✍ Scribed by Strey, Reinhard; Viisanen, Yrjö; Aratono, Makoto; Kratohvil, Josip P.; Yin, Qi; Friberg, Stig E.


Book ID
120404456
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
89 KB
Volume
103
Category
Article
ISSN
0022-3654

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The derivation of an exact "generalized kinetic equation" for the pseudeunimolecular react&n X + A =+ B f X is presented. When the limits of long time and low X-particle density are taken, this equation reduces to the usual form of a chemical rate equation. The correlation function type expressions