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On the Nature of the Intermediates and the Role of Chloride Ions in Pd-Catalyzed Allylic Alkylations: Added Insight from Density Functional Theory †

✍ Scribed by Fristrup, Peter; Ahlquist, Mårten; Tanner, David; Norrby, Per-Ola


Book ID
125931383
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
929 KB
Volume
112
Category
Article
ISSN
1089-5639

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## Abstract A new class of chiral __C__~2~‐symmetrical diamino‐oligothiophenes is described to be effective in catalyzing Pd‐mediated asymmetric allylic alkylations in a highly enantioselective manner. The combination of experimental as well as crystallographic evidence revealed the key role played