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On the natural occurrence of (−)-3-carene, a component of termite defense secretions

✍ Scribed by I. Valterová; J. Vrkoč; M. Lindström; T. Norin

Book ID
105088005
Publisher
Springer
Year
1992
Tongue
English
Weight
215 KB
Volume
79
Category
Article
ISSN
0028-1042

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Stereoselective synthesis of cubitene (11, a novel diterp-ene isolated from defense secretion of termites, has been accomplished using an intramolecular reaction of a-sulfenyl carbanion vi th epoxide. Hydride reduction of the ketone 11 obtalned by Claisen rearrangement occurred in unexpectedly high