In polyatomic molecules, the Wigner-van Neumann non-crossmg rule is generally relaxed because of the cxistcncc of more than a single nuclear coordinate. Potential energy surfaces may or may not intersect. There is an interesting class of states where an intersection cannot occur if only the dominant
✦ LIBER ✦
On the multidimensional “avoided surface crossing” problem
✍ Scribed by J. Vojtík; R. Polák
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 484 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
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