✦ LIBER ✦
On the Michaelis–Menten behavior of pyridinium chloro chromate oxidations: Oxidation of dimethyl, dipropyl, and diphenyl sulfide in chlorobenzene–nitrobenzene mixtures
✍ Scribed by G. P. Panigrahi; D. D. Mahapatro
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 434 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
Abstract
The kinetics of oxidation of dimethyl, dipropyl, and diphenyl sulfides by pyridinium chloro chromate in chlorobenzene–nitrobenzene mixtures are reported. The rate data show Michaelis–Menten behavior. The oxidation process is catalyzed by the organic acids like dichloro and trichloro acetic acids. The rate‐determining step appears to be a unimolecular decomposition of a complex of the reactants.