## Abstract The cobaltβcatalyzed alternating copolymerization of epoxides and CO is a novel, direct approach to aliphatic polyesters, such as poly(hydroxybutyrate) (PHB). This reaction was found to be catalyzed by Ph~3~Si[Co(CO)~4~] (4) and pyridine affording in a first step the stable monoβinserti
On the Metal Catalyzed Deposition of Carbon from Carbon Monoxide
β Scribed by J. F. Henry
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 347 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0037-9646
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## Abstract The commercial production of glycerol has increased considerably for several years, because of its rising inevitable formation as a byβproduct of biodiesel. For the effective utilization of glycerol, a new synthesis of glycerol carbonate (4βhydroxymethylβ2βoxoβ1,3βdioxolane) that is use
Table 1. Iy5Pt-NMR data for some platinum-tin complexes [a]. 1runs-[PtC1(SnC1~)(PEt~)~] [c] 28954 -4780 -864 Irun~-[Pt(SnCl~)~(PEt,)~] [d] 20410 -5152 -618 [el trans-[PtH(SnCla)(PEt,)2J [fl 9 067 -5302 -426 truns-[PtH(SnCb)(PPh2CH2Ph)2] [fl 10955 -5322 -428 I~u~~-[P~(C(CO,E~)==CHCOZE~)(S~C~~)(PP~~)