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On the mechanisms of degenerate halogen exchange in phosphorus(iii) halides

✍ Scribed by Renard, Sylvie L.; Fisher, Julie; Kilner, Colin A.; Thornton-Pett, Mark; Kee, Terence P.


Book ID
120514585
Publisher
The Royal Society of Chemistry
Year
2002
Tongue
English
Weight
378 KB
Volume
14
Category
Article
ISSN
1472-7773

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Reactions of SnCl 2 with the complexes cis-[PtCl 2 (P 2 )] (P 2 ΒΌ dppf (1,1'-bis(diphenylphosphino)ferrocene), dppp (1,3-bis(diphenylphosphino resulted in the insertion of SnCl 2 into the PtΓ€Cl bond to afford the cis-[PtCl(SnCl 3 )(P 2 )] complexes. However, the reaction of the complexes cis-[PtCl