✦ LIBER ✦

On the Mechanism of the Reaction of Organic Azides with Transition Metals: Evidence for Triplet Nitrene Capture

✍ Scribed by Mahdi M. Abu-Omar; Catherine E. Shields; Nicola Y. Edwards; Rebecca A. Eikey

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 130 KB
Volume: 117
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200462647

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

On the Mechanism of the Reaction of Orga

On the Mechanism of the Reaction of Organic Azides with Transition Metals: Evidence for Triplet Nitrene Capture

✍ Mahdi M. Abu-Omar; Catherine E. Shields; Nicola Y. Edwards; Rebecca A. Eikey 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 130 KB 👁 1 views

The Mechanism of Interaction of Triplet

The Mechanism of Interaction of Triplet 3-Methylcyclohex-2-en-1-one with Maleo- and fumarodinitrile: Evidence for Direct Formation of Triplet 1,4-Biradicals in [2 + 2] Photocyclo- additions without the Intermediacy of Exciplexes

✍ Prof. David I. Schuster; Dr. George E. Heibel; Dr. Jan Woning 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 379 KB 👁 2 views

Mechanism of the Reaction of the [W3S4H3

Mechanism of the Reaction of the [W3S4H3(dmpe)3]+ Cluster with Acids: Evidence for the Acid-Promoted Substitution of Coordinated Hydrides and the Effect of the Attacking Species on the Kinetics of Protonation of the Metal-Hydride Bonds

✍ Manuel G. Basallote; Marta Feliz; M. Jesús Fernández-Trujillo; Rosa Llusar; Vice 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 187 KB

## Abstract The cluster [W~3~S~4~H~3~(dmpe)~3~]^+^ (1) (dmpe=1,2‐bis(dimethylphosphino)ethane) reacts with HX (X=Cl, Br) to form the corresponding [W~3~S~4~X~3~(dmpe)~3~]^+^ (2) complexes, but no reaction is observed when 1 is treated with an excess of halide salts. Kinetic studies indicate that th