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On the mechanism of the photoisomerization reaction of aryl substituted indenes

✍ Scribed by Albert Padwa; Steven Goldstein; Roman Loza; Mitchell Pulwer

Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
198 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis

The mechanism of the phototransposition reaction of a number of arylalkyl substituted indenes has been found to be markedly dependent on the nature and location of the substituent groups. Considerable interest has been focused in recent years on phototransposition reactions which have the net effect of interchanging atoms within a five-membered ring'. Examples have been reported for variously substituted heterocycles2 and cyclopentadiene derivatives3. Bicyclo[2.l.O]pent-2-enes and 3-vinylcyclopropene analogs are the most commonly invoked intermediates responsible for these rearrangements; in some instances, such molecules have been detected and characterized.' Recently, we described the photochemical rearrangement of indenes

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Further work needs to be done in order to establish this ooint.

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