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On the mechanism of the oxidation of graphite by molecular oxygen

✍ Scribed by R Schlögl; G Loose; M Wesemann


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
756 KB
Volume
43
Category
Article
ISSN
0167-2738

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The halogenated Porphyrin, 2,12,13,17,l5,~~hy~nat~iron(III) chloride, [ Fe( TPPPBr,)Cl] , catalyzes the oxidation of cyclohexene in the presence of molecular oxygen or iodosobenzene. With PhIO, 77% epoxide is observed, consistent with a mechanism involving a high-valent metaI-oxo species. With dioxy