✦ LIBER ✦

On the mechanism of the formation of fulvenallene from the gas phase pyrolysis of indazole. The gas phase pyrolysis of n-deuterio-3-methylindazole.

✍ Scribed by W.D. Crow; M.N. Paddon-Row

Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 212 KB
Volume: 13
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)94004-3

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✦ Synopsis

A ei@fiwnt property of pherurlnttrene alldpbe?gloarbene generatedlnthegaepbaee 8t &llperatuFee )7m" ie thdl' abilit# to lll&gO l'il@ OOll~tiOn to gin OyWLOOyOlOpe&8diene'~2 (2s) and ful venallens Q) plue et~layclopent.sdime (2b) reepeotively. However it rae dieoovered subeequently that the gas pheee plrrolysla of benaotrissole'l yielded &) end that ind8solee and 1,2-lnd8uedione9 (4) both &Irre (2) in mod Jields. The =eoImiau of the80 raaotiaas we similar and nay be disoueaed in tenw of the deoompoei& of indssole, the more likely pathray being outlined below In S&me 1.

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