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On the Mechanism of the Deposition of Silica by Pyrolytic Decomposition of Silanes

โœ Scribed by Klerer, Julius

Book ID
124063212
Publisher
The Electrochemical Society
Year
1965
Tongue
English
Weight
513 KB
Volume
112
Category
Article
ISSN
0013-4651

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๐Ÿ“œ SIMILAR VOLUMES

The deposition of pyrolytic carbon in si
The deposition of pyrolytic carbon in silica reactors
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## When surface carbons are produced by the pyrolysis of gaseous hydrocarbons in a silica tube heated to about lOOO"C, spectrographic analysis shows the presence of up to 1% silicon even when the carbon is deposited on a metal substrate. It seems likely that hydrocarbon radicals react with silica

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The homogeneous gas-phase decomposition kinetics of silane has been investigated using the single-pulse shock tube comparative rate technique (T = 1035-1184ยฐK, P ~d = 4000 Torr). The initial reaction of the decomposition SiH4 ! + SiHz + H2 is a unimolecular process in its pressure fall-off regime w