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On the mechanism of the copper-catalysed hydro-genation; a reinterpretation of published data

✍ Scribed by Albert J. Dijkstra


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
71 KB
Volume
104
Category
Article
ISSN
1438-7697

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The mechanism of copper(I)-catalyzed olefin cyclopropanation with diazomethanes has been studied at the BP86/AE1 level of density-functional theory. For the model system Cu(diazabutadiene) + + ethene + diazomethane, copper carbene complexes are confirmed as viable intermediates, with rate-determinin