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On the mechanism of the Baeyer-Villiger oxidation of ketones by bis(trimethylsilyl) peroxomonosulfate. Intermediacy of dioxiranes

✍ Scribed by Camporeale, Michele; Fiorani, Tiziana; Troisi, Luigino; Adam, Waldemar; Curci, Ruggero; Edwards, John O.

Book ID
115537696
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
761 KB
Volume
55
Category
Article
ISSN
0022-3263

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A theoretical study on the mechanism of
A theoretical study on the mechanism of the baeyer–villiger type oxidation of 7-phosphanorbornene 7-Oxides
✍ Attila Kovács; Dénes S. Nemcsok; György Keglevich 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 444 KB

## Abstract DFT computations have been performed on selected stationary points of the reaction path (reactants, intermediates, and products) of the Baeyer–Villiger type oxidation of 7‐phosphanorbornene 7‐oxide derivatives. Our computations justified the relevance of a Criegee‐type intermediate form