✦ LIBER ✦

On the mechanism of the azide-bromine reaction in aqueous medium

✍ Scribed by Zeev B. Alfassi

Publisher: John Wiley and Sons
Year: 1987
Tongue: English
Weight: 180 KB
Volume: 19
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550190809

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✦ Synopsis

Vivekanandam and coworkers [ 11 studied the reaction of azide anion with bromine in aqueous solution by measuring the nitrogen gas evolution. In the presence of excess N3, they found that:

The stoichiometry is Br2 + 2N3 -2Br + 3N2.

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