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On the Mechanism of the Acid/Base-Catalyzed Thermal Cis − Trans Isomerization of Methyl Orange

✍ Scribed by Sanchez, Ana M.; Barra, Mónica; de Rossi, Rita H.


Book ID
120207920
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
90 KB
Volume
64
Category
Article
ISSN
0022-3263

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Quantumshemical calculations have been performed for rotations around the different CC bonds of streptocyanine eations and of various ion pairs of TMC+ and PM? with Cl-as the gegenion (counterion) in order to explain the experimentally well known temperature dependence of the activation energy for t