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On the mechanism of racemisation of dichlorobis(ethylenediamine)-metal chlorides [metal = cobalt(III) or chromium(III)] in the solid state

✍ Scribed by D. Banerjea; J. C. Bailar


Publisher
Springer
Year
1985
Tongue
English
Weight
310 KB
Volume
10
Category
Article
ISSN
0340-4285

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✍ Gehan Moustafa El-Subruiti 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 145 KB 👁 1 views

## Abstract The kinetics of solvolysis of __trans__‐dichlorobis(__N__‐methylethylenediamine)cobalt(III) complex have been investigated in aqua‐organic solvent media (0–60% (v/v) cosolvent) at 25 ≤ t°C ≤ 60, using __n__‐propanol and __tert__‐butyl alcohol as cosolvents. The first‐order rate constant