The stoichiometry and kinetics of the oxidation of thiourea (SC(NH2)z) by chlorine dioxide (ClOz) have been studied by uv-vis spectrophotometry using conventional and stopped-flow mixing techniques at 25.0 ? O.l"C, pH 0.3-4.8. In high acid and initial 10 : 1 molar ratio of thiourea to chlorine dioxi
โฆ LIBER โฆ
On the mechanism of oxidation of thioureas
โ Scribed by P.N.Kesavan Nambisan
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 113 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Oxidation of binary mixtures of g-diarylthioureas and thiourea is known to yield ~-amino-4-ary1-5-ary1imino-1,?,4-~*-thiadiazo1ines (Ia)'. !Phe reaction
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