On the mechanism of lithium amide-induced rearrangements of 4-substituted cyclopentene oxides to cyclopentenols

✍ Scribed by David M. Hodgson; Andrew R. Gibbs

• Book ID: 104258372
• Publisher: Elsevier Science
• Year: 1997
• Tongue: French
• Weight: 216 KB
• Volume: 38
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(97)10358-6

✦ Synopsis

The preparation and lithium amide-induced rearrangements of epoxides 4, 10 (R = Bn, TBS) are described, providing insight into the rearrangement mechanisms which operate in such systems.