✦ LIBER ✦

On the mechanism of heterogeneous relaxation of vibrationally excited nitrogen molecules

✍ Scribed by V.I. Egorov; Yu.M. Gershenzon; V.B. Rozenshtein; S.Ya. Umanskii

Publisher: Elsevier Science
Year: 1973
Tongue: English
Weight: 347 KB
Volume: 20
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(73)85221-2

No coin nor oath required. For personal study only.

✦ Synopsis

The N2 vibrational deactivation probability E in the case of a collision with a glass surface has been measured over the temperature range 282-603°K

for different values of pressure. The observed temperature and pressure dependence of e is interpreted in terms of twc different additive mechanisms of the heterogeneous vibrational reLzx3 tion. One of these is connected with the physical and the other with the chemical adsorption of the vibrationalIy excited N2 molecule.

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