On the mechanism of deoxygenation of secondary alcohols by tin hydride reduction of methyl xanthates and other thiocarbonyl derivatives

✍ Scribed by Derek H.R. Barton; Jang Doo Ok; Joseph Cs. Jaszberenyi

• Publisher: Elsevier Science
• Year: 1990
• Tongue: French
• Weight: 240 KB
• Volume: 31
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)94480-0

✦ Synopsis

The room temperature deoxygenation of xanthates and thionocarbonates using (n-B~las"n"-HN.,,~t3~~~t~~~co~~ bg= studied, especially with original conception of tin radical attack on thiocarbonyl is confirmed.