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On the Mechanism for the Hydrogenation of Olefins on Transition-Metal Surfaces: The Chemistry of Ethylene on Pt(111) †

✍ Scribed by Zaera, Francisco


Book ID
126234782
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
468 KB
Volume
12
Category
Article
ISSN
0743-7463

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The reaction of C2H 4 on Pt{111} at 300 K has been investigated by single crystal adsorption calorimetry. The initial heats of adsorption and the initial sticking probability are 174 kJ/mol and 0.67 respectively. The adsorption heat versus coverage data shows a remarkable minimum which serves as a b