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On the Mechanism and Scope of a Novel Nitroolefin Rearrangement

✍ Scribed by Alfred Hassner; William Chau


Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
179 KB
Volume
23
Category
Article
ISSN
0040-4039

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On the mechanism of the Elbs peroxydisul
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Semiempirical calculations show that the intermediate formed by reaction between peroxydisulfate anion and the phenolate ion (the Elbs oxidation) is the species resulting from reaction of the tautomeric carbanion rather than the one resulting from attack by the oxyanion. This is confirmed by synthes