On the increase of the vibrational atomi
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Lothar Scha¨fer; S.J. Cyvin; J. Brunvoll
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Article
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1972
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Elsevier Science
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English
β 172 KB
When a free molecule becomes a ligand in a complex molecule, the complex formation leads to an increase of the mean square cartesian displacements of its atoms. An explanation for this fundamental phenomenon is given. The increase in the mean square cartesian displacements by complexation can always