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On the mass independence of the mean-square atomic displacement in the classical limit

✍ Scribed by Feldman, J. L.


Book ID
114521612
Publisher
International Union of Crystallography
Year
1974
Weight
206 KB
Volume
30
Category
Article
ISSN
0567-7394

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On the increase of the vibrational atomi
✍ Lothar SchaΒ¨fer; S.J. Cyvin; J. Brunvoll πŸ“‚ Article πŸ“… 1972 πŸ› Elsevier Science 🌐 English βš– 172 KB

When a free molecule becomes a ligand in a complex molecule, the complex formation leads to an increase of the mean square cartesian displacements of its atoms. An explanation for this fundamental phenomenon is given. The increase in the mean square cartesian displacements by complexation can always