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On the magnetic interactions between ions with degenerate π-orbitals

✍ Scribed by Nobuko Fuchikami; Ruud Block

Publisher
Elsevier Science
Year
1983
Weight
776 KB
Volume
119
Category
Article
ISSN
0378-4363

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📜 SIMILAR VOLUMES

Magnetic Exchange between Orbitally Dege
Magnetic Exchange between Orbitally Degenerate Metal Ions: The Problem of Magnetic Anisotropy
✍ J.J. Borrás-Almenar; E. Coronado; J.M. Clemente-Juan; A.V. Palii; B.S. Tsukerbla 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 545 KB

In this paper we show that a strong magnetic anisotropy appears in exchange mixed+valence clusters containing orbitally degenerate metal ions. Combining an e4ective Hamiltonian approach with the technique of the irreducible tensor operators (ITO) and pseudoangular momentum representation we have sol