On the loss of methyl radical from one of the isomeric molecular ions of 2-cyclohexen 1-ol.
✍ Scribed by C. Lignac; J.C. Tabet
- Publisher
- Elsevier Science
- Year
- 1983
- Weight
- 244 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0020-7381
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## Abstract The electron impact mass spectra of 2‐cyclohexen‐1‐ol and of several of its ^2^H and ^13^C labelled analogues show that the molecular ions lose a methyl radical by a completely different means from the mechanism described previously. Moreover, the retro Diels–Alder reaction also proceed
## Abstract Relative rate coefficients for the reactions of OH with 3‐methyl‐2‐cyclohexen‐1‐one and 3,5,5‐trimethyl‐2‐cyclohexen‐1‐one have been determined at 298 K and atmospheric pressure by the relative rate technique. OH radicals were generated by the photolysis of methyl nitrite in synthetic a