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On the longevity of H-mediated ferromagnetism in Co doped : A study of electronic and magnetic interplay

โœ Scribed by R.K. Singhal; A. Samariya; Sudhish Kumar; Y.T. Xing; D.C. Jain; U.P. Deshpande; T. Shripathi; Elisa Saitovitch; C.T. Chen


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
583 KB
Volume
150
Category
Article
ISSN
0038-1098

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โœฆ Synopsis


Recent studies on dilute magnetic semiconductors have largely been focused on hydrogen induced giant magnetization. On the contrary, there are hardly any attempts to establish whether the H-induced magnetization is a permanent feature or likely to degrade with time. This aspect warrants a firm confirmation prior to planning their possible applications in spintronics and microelectronics. Motivated by this, we have systematically investigated this behaviour in Co doped TiO 2 . In one study, we gave successive re-heat treatment to hydrogenated pellets and studied their magnetic, transport and electronic properties versus re-heating time. In another, we stored the hydrogenated sample in dry atmosphere for several months and studied the ageing effect on the induced ferromagnetism. The H-induced magnetization quickly vanishes upon re-heating the specimen; in addition, it also tends to degrade gradually with passage of time. The electronic and transport properties show a close parallelism, without any departure from structural properties. On the other hand, the Co-induced ferromagnetism, albeit a weak effect, does not show such degradation effects. As regards the mechanism of ferromagnetism, the oxygen vacancies are suggested to mediate the coupling.


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