✦ LIBER ✦
On the laser-femtochemistry approach to coherent molecular vibrations. Model simulations for Ni[C2D4] → Ni + C2D4
✍ Scribed by J. Manz; B. Reischl; T. Schröder; F. Seyl; B. Warmuth
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 738 KB
- Volume
- 198
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The metal-ligand bond of Ni [ C2Dl] may be broken by ultrafast pump laser pulses on a femtosecond ( a25 fs) time scale. As a consequence the product C2D4 is prepared with coherent out-of-plane bending vibrations, which can be monitored by ultrafast probe lasers. The effect is simulated by representative wavepackets propagated on the relevant potential energy surfaces of Ni [ C,D,] using a simple, two-dimensional model.
NVJbl a
NitC2D4.