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On the kinetics of the transition metal catalyzed decomposition of secondary hydroperoxides

✍ Scribed by I. P. Hajdu; I. Nemes; L. Sümegi; T. Vidóczy; D. Gál

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
467 KB
Volume
13
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

A general mechanism was proposed for the title reactions which describes the kinetics of hydroperoxide decomposition as well as product accumulation throughout the whole reaction period in an analytical form. The following catalytic steps were included: magnified image where the deactivation takes place as a result of radical–catalyst interaction inside the cage. The resulting equations give satisfactory description of the literature data in the case of various catalysts and hydroperoxides.

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