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On the kinetics and mechanism of Nb(V) hydrolysis

✍ Scribed by Otávio L. Bottecchia; Julien F. C. Boodts

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
376 KB
Volume
25
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

Kinetics of Nb(V) hydrolysis in MgCl~2~, Mg(ClO~4~)~2~ mixtures has been investigated by electroanalytical methods and the rate constants determined. A hydrolysis model based on species postulated in the literature is proposed. Resolution of the corresponding differential equations led to results consistent with experimental data obtained from polarographic current vs. time curves. © 1993 John Wiley & Sons, Inc.

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