On the kinetic coupling and mechanism of aromatic ring hydrogenation
β Scribed by Smeds, S. ;Salmi, T. ;Murzin, D. Yu.
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 217 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0133-1736
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## Abstract The rate of hydrogenation of cyclohexene, catalyzed by CoH~3~(PPh~3~)~3~, has been measured under various conditions and, based on these data, a mechanism has been postulated. For the individual steps of the mechanism enthalpy and entropy differences have been determined. The interpreta
4 low-temperature matrix isolation method has been developed which makes possible the isolation and detection of HO2 radicals from a gas-phase radical chain-reaction system conta-ining atomic H, 0 and O H radicals as well. The formation of HOt radicals is demonstrated in the rarified hydrogen flame.