On the introduction of the rotation-vibration coupling in diatomic molecules and the factorization method
โ Scribed by Badawi, M; Bessis, N; Bessis, G
- Book ID
- 124171230
- Publisher
- Institute of Physics
- Year
- 1972
- Tongue
- English
- Weight
- 192 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0022-3700
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๐ SIMILAR VOLUMES
## Abstract A solution of the wave equation for the nuclear motion of a diatomic molecule with an exponential potential function and the rotational term included has been performed by the SchrรถdingerโInfeldโHull factorization method. Two different procedures have been followed for the factorization
The inductive properties of a non-polar diatomic molecule in a static non-uniform electric field are best described in terms of its dipole polarizability (a), second hyperpolarizability (y), quadrupole-quadrupole polarizability (C) and dipole-dipole-quadrupole polarizability (B). We present formulae
The commutator perturbation method, an algebraic version of the Van Vleck-Primas perturbation method, expressed in terms of ladder operators, has been applied to solving the eigenvalue problem of the Hamiltonian describing the vibrational-rotational motion of a diatomic molecule. The physical model