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On the interpretation of vibrational relaxation measurements

✍ Scribed by W.D. Breshears

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
296 KB
Volume
20
Category
Article
ISSN
0009-2614

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✦ Synopsis

The relative relaxation rates of vibrational lcvcl populations following establishment of a Boltzmann vibrational distribution by rapid vibration-vibration energy transfer are shown to depend on the nature and extent of the departure from equilibrium. The only kinetic information obtainable under such conditions is :, the rela..ation time of the vibrational enern. The implications for interpretation of Iaser-induced vibrational tluorescence ma_xrements arc cmphasized.

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