✦ LIBER ✦

On the intermolecular potential in solid N2. II. Libronic frequencies

✍ Scribed by Myron J. Mandell

Publisher: Springer US
Year: 1975
Tongue: English
Weight: 338 KB
Volume: 18
Category: Article
ISSN: 0022-2291
DOI: 10.1007/bf00118157

No coin nor oath required. For personal study only.

✦ Synopsis

The librational frequencies of solid el-nitrogen are calculated using an RPA formalism and a potential expressed as a multipolar expansion. As was previously suggested, inclusion of higher-than-quadrupolar terms in the hard-core potential is required for agreement with experiment. The relative values of the "nonelectric" quadrupole-quadrupole interactions determine the precise frequencies. The Gruneisen parameters -c~(ln og)/c~(ln V) can be explained by postulating a volume-independent hexadecapole-monopole potential. Such an assumption is partially justified by libron-phonon interactions, which are shown to play a significant role in determining the effective multipolar potentials.

📜 SIMILAR VOLUMES

On the intermolecular potential in solid

On the intermolecular potential in solid N2

✍ Myron J. Mandell 📂 Article 📅 1974 🏛 Springer US 🌐 English ⚖ 322 KB

A method for the separate computation of

A method for the separate computation of intermolecular vibrational frequencies with application on the H2O…HF and (H2O)n (n = 2–6) complexes

✍ Klaus-Peter Schröder 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 894 KB

Glory structure in the N2N2 total integ

Glory structure in the N2N2 total integral scattering cross section. A test for the intermolecular potential energy surface

✍ David Cappelletti; Franco Vecchiocattivi; Fernando Pirani; Frederick R.W. McCour 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 508 KB

The first measurement of the glory structure of the total integral cross section for the scattering of N2 against N2 is reported for the collision velocity range 500-3000 m s -l. A comparison is made between the measured structure and calculations carried out within the infinite-order sudden dynamic

Copper(II) complexes with tridentate N-(

Copper(II) complexes with tridentate N-(benzoyl)-N′-(salicylidine)-hydrazine and monodentate N-heterocycles: Investigations of intermolecular interactions in the solid state

✍ Sunirban Das; Samudranil Pal 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 924 KB

Ternary copper(II) complexes having the general formula [Cu(bhs)(hc)], with a tridentate Schiff base, N-(benzoyl)-N 0 -(salicylidine)hydrazine (H 2 bhs) and monodentate N-heterocycles (hcZ3,5-dimethylpyrazole, pyrazole, imidazole, and pyridine), are described. The complexes were characterized by ele

Dielectric anomalies of solid CO and N2

Dielectric anomalies of solid CO and N2 in the audio frequency range

✍ S. Pilla; J.A. Hamida; K.A. Muttalib; N.S. Sullivan 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 126 KB

Audio frequency dielectric constant measurements of CO and N in their solid phases are presented. Anomalous 2 temperature dependence of the dielectric constant in the a-phases of both CO and N and strong hysteresis effects above an 2 onset temperature T , 42 K in the b-phase of pure N have been obse

On the emission spectrum of atomic N in

On the emission spectrum of atomic N in solid N2: Vibrational relaxation rates of N2

✍ O. Oehler; K. Dressler 📂 Article 📅 1971 🏛 Springer 🌐 English ⚖ 180 KB