I Highly resolved phosphorcsccncc and optical-microwave doublcrcsonancc spectra of thio\anthonc xc rcportcd. In contrast to related molecules, not only thcz sublevel, but also they sublevel tirries substanhal oscillator strength, where as intersystcm crossing still is highly selective, rmching the t
On the inhomogeneous and homogeneous broadenings of optical and ODMR transitions of triplet states in solids
โ Scribed by J.P. Lemaistre; A.H. Zewail
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 457 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
X simple mccbanbm for tbc broaicnin~ of optic~t and ODOR kmsitions ofgucst molccuks in botb Iatticcs is prorided. Xccording lo this mwIxmism the broadrning rcsuhs from the ~QII~~O!II spin-orbital intcmctions caused by electronic cncrgy fluctuations ~inh~mo~cnrous) in the sin;Ict and triplet st.Hrks. Comparison of the theorrtical findings of the model with e\perimnenrr is made and new predicticns are gikm.
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