On the infrared spectroscopic determination of self- and interassociation equilibrium constants used in the prediction of the phase behavior of hydrogen bonded polymer blends

The prediction of hydrogen bonded polyme

The prediction of hydrogen bonded polymer blend phase behavior using equilibrium constants determined from low molar mass analogues

✍ Michael M. Coleman; Kevin S. Guigley; Paul C. Painter 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 109 KB 👁 1 views

Equilibrium constants determined from low molecular weight mixtures are used to predict the phase behavior of analogous polymer blends. Due consideration is given to intramolecular screening and functional group accessibility, factors that are a direct consequence of chain connectivity.