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On the infrared and raman spectra of water in the region 5–250 cm−1

✍ Scribed by P.A. Madden; R.W. Impey

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
466 KB
Volume
123
Category
Article
ISSN
0009-2614

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✦ Synopsis

The far-infrared absorption coefficient and R(w) representation of the Raman spectrum are calcuiated for the interactioninduced dipole and polarizability of water by computer simulation, using the MCY potential. A simple dipole-induced drpoie model is able to reproduce experimentally observed bands at 60 and 200 cm-'. It is shown that these bands may be associated with oscillations in the centre-of-mass velocity correlation function.

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