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On the influence of UV-irradiation on the keto-enol equilibrium of ethylacetoacetate in solution

✍ Scribed by Peter Markov; L. Shishkova; Z. Zdravkova


Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
168 KB
Volume
13
Category
Article
ISSN
0040-4039

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Substituent effects in keto-enol tautome
✍ M. Bassetti; G. Cerichelli; B. Floris πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 437 KB

The enol content and equilibrium free energies for the keto-enol tautomerism have been determined for a series of 1,3-diketones, at 40 OC, in deuterochloroform and dimethylsulfoxide-d (DMSO), by lH n.m.r.. Compounds containing methyl, phenyl, t-butyl, E-thienyl, trifluorome t hyl and ethoxy groups h